THE RATE OF CHEMICAL REACTIONS
Every chemical reaction requires some time for its completion, but some reactions are very fast and others very slow. Reactions between ions in solution without change in oxidation state are usually extremely fast. An example is the neutralization of an acid by a base, which proceeds as fast as the solutions can be mixed. Presumable nearly every time a hydronium ion collides with a hydroxide ion reaction occurs, and the number of collisions is very great, so that there is little delay in the reaction. The formation of a precipitate, such as that of silver chloride when a solution containing silver ion is mixed with a solution containing chloride ion, may require a few seconds, to permit the ions to diffuse together
to form the crystalline grains of the precipitate. On the other hand, ionic oxidation-reduction reactions are sometimes very slow. An example is the oxidation of stannous ion by ferric ion. This reaction does not occur every time a stannous ion collides with one or two ferric ions. In order for the reaction to take place, the collision must be of such a nature that electrons can be transferred from one ion to another, and collisions, which permit this electron transfer to occur, may be rare.
The factors, which determine the rate of a reaction, are manifold. The rate depends not only upon
the composition of the reacting substances, but also upon their physical form, the intimacy of their mixture, the temperature and pressure, the concentrations of the reactants, special physical circumstances such as irradiation with visible light, ultraviolet light, X-rays, neutrons, or other waves or particles, and
the presence of other substances which affect the reaction but are not changed by it/catalysts/.
Most actual chemical processes are very complicated, and the analysis of their rate is very difficult.
As reaction proceeds the reacting substances are used up and new ones are formed; the temperature of the system is changed by the heat evolved or absorbed by the reaction; and other effects may occur which influence the reaction in a complex way. For example, when a drop of a solution of potassium permanganate is added to a solution containing hydrogen peroxide and sulfuric acid no detectable reaction may occur for several minutes. The reaction speeds up, and finally the rate may become so great
as to decolorize a steady steam of permanganate solution as rapidly as it is poured into the reducing
solution. This effect of the speeding up of the reaction is due to the vigorous catalytic action of the products of permanganate ion reduction: the reaction is rapidly accelerated as soon as they are formed.
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