HYDROCARBONS
Hydrocarbons are compounds containing only carbon and hydrogen atoms. The simplest hydrocarbon is methane, CH4. Its molecules are tetrahedral, the four hydrogen atoms lying at the corners
of a regular tetrahedron around the carbon atom, and connected with the carbon atom with single bonds.
Methane is a gas, which occurs in natural gas, and is used as a fuel. It is also used in large quantities for
the manufacture of carbon black, by combustion with a limited supply of air. The hydrogen burn to water, and the carbon is deposited as very finely divided carbon, which finds extensive use as filler for rubber
for automobile tires.
Methane is the first member of a series of hydrocarbons having the general formula CnH2n+2, called
the methane series or paraffin series. The compounds of this series are not very reactive chemically. They occur in complex mixtures called petroleum. The molecules heavier than ethane are characterized by containing carbon atoms attached to one another by single bonds. The lighter members of the paraffin series are gases, the intermediate members are liquids, and the heavier members are solid or semi-solid substances. Gasoline is the heptane-nonane mixture, and kerosene the decane-hexadecane mixture. Heavy fuel oil is a mixture of paraffins containing twenty or more atoms per molecule. The lubricating oils and solid paraffin are mixtures of still larger paraffin molecules.
The substance ethylene, C2H4, consists of molecules in which there is a double bond between the two carbon atoms. This double bond confers upon the molecule the property of much greater chemical reactivity than is possessed by the paraffins. Because of this property of readily combining with other substances, ethylene and related hydrocarbons are said to be unsaturated.
Acetylene is the first member of a series of hydrocarbons containing triple bonds. Aside from acetylene, these substances have not found wide use, except for the manufacture of other chemicals.
The hydrocarbons, the molecules of which contain a ring of carbon atoms, are called cyclic hydrocarbons. Cyclohexane, C6H12, is representative of this class of substances. It is a volatile liquid, closely similar to normal hexane in its properties.
Another important hydrocarbon is benzene, having the formula C6H6. It is a volatile liquid/ b.p.
800C/, which has an aromatic odor. For many years there was discussion about the structure of the benzene molecule. August Kekule suggested that the six carbon atoms are in the form of a ring, and this
has been verified: diffraction studies have shown that the six atoms form a regular planar hexagon in space, the six hydrogen atoms being bonded to the carbon atoms, and forming a larger hexagon. Kekule suggested that, in order for a carbon atom to show its normal quadrivalence, the ring contains three single bonds and three double bonds in alternate positions. Other hydrocarbons, derivatives of benzene, can be obtained by replacing the hydrogen atoms by methyl groups or similar groups. Benzene and its derivatives are used in the manufacture of drugs, explosives, photographic developers, plastics, synthetic
dyes, and many other substances.
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