CHEMICAL NOMENCLATURE
A systematic nomenclature was devised towards the end of the 18th century. Elements already known retained their old names, e.g. silver, tin, gold, mercury, etc., but newly discovered elements generally have their names ending in -um if they are metals, and-on if they are non-metals/e.g. sodium, potassium, argon /.
The names of compounds are formed from those of their components so as to indicate their composition. In the names of binary compounds /i.e., compounds of two elements/ the name of the metal comes first, followed by that of the other element ended in -ide, e.g. sodium chloride /NaCl/, zinc oxide
/ZnO/, aluminum oxide /Al2O3/. When a metal forms two compounds with oxygen, the two oxides are distinguished by adding -ous and -ic to the Latin name of
the metal, signifying the lower and higher oxidation states respectively, e.g., cuprous oxide /Cu2O/, cupric oxide /CuO/, and ferrous oxide /FeO/, ferric oxide /Fe2O3/. The salts corresponding to cuprous oxide are called cuprous salts, e.g. cuprous chloride and cupric chloride. Another way of distinguishing between different compounds of the same element is by the use of the Greek prefixes to the names of the elements. These prefixes are as follows: mono-, di-, tri-, tetra-, penta-, hexa-, hepta-, octo-. To these we may add the Latin hemi-, meaning one half, and sesqui-, meaning one and a half, and per-. By the use of these prefixes we can designate the compounds more precisely than by means of the prefixes -ous and -ic, especially when more than two compounds exist. As examples of the use of these prefixes we may mention carbon monoxide /CO/ and carbon dioxide /CO2/, phosphorus trichloride /PCl3/ and phosphorus pentachloride /PCl5/, chromium sesquioxide /Cr2O3/ and chromium trioxide /CrO3/, lead hemioxide /Pb2O/, hydrogen peroxide /H2O2/.
Oxides, which form salts with acids, are known as basic oxides; by combination with water, basic oxides form bases. These contain the metal united with the group of atoms -OH/ the hydroxyl group/; they are, therefore, called hydroxides. Thus NaOH is sodium hydroxide, Cu(OH)2 is copper hydroxide,
and the compounds Fe(OH)2 and Fe2O3.H2O are ferrous hydroxide and ferric hydroxide, respectively.
The endings -ous, -ic are also applied to acids, the -ous acid containing less oxygen than the -ic acid, e.g. sulphurous acid /H2SO3/ and sulfuric acid /H2SO4/, chlorous acid /HClO2/. In addition to HClO2 and HClO3, the acids having the formulas HClO and HClO4 are also known, the former having the name hypochlorous acid, the latter being designated by the name perchloric acid.
Salts are named in relation to the acids from which they are derived according to the following
rules:
1. If the name of the acid ends in -ous, the name of the salt ends in -ite/ sodium chlorite, NaClO2/.
2. If the name of the acid ends in -ic, the corresponding salt ends in -ate/ sodium chlorate, NaClO3/
3. If the name of the acid involves also a prefix such as per- or hypo-, the prefix is retained on the name of the salt/ sodium hypochlorite, NaClO, and sodium perchlorate, NaClO4/. Accordingly, salts of sulfurous acid are called sulfites, those of sulfuric acid, sulfates. Salts of phosphorous acid
are phosphites, of phosphoric acid, phosphates, etc.
0 comments:
Post a Comment